期刊
JOURNAL OF CATALYSIS
卷 364, 期 -, 页码 345-353出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2018.05.014
关键词
Ru(III); Olefin metathesis; DCPD; ROMP; RCM
资金
- National Science Centre (Poland) [DEC-2012/04/A/ST5/00594]
- European Union from the European Regional Development Fund under the Operational Programme Innovative Economy
Upon activation with C2Cl6 known latent Ru metathesis catalyst LatMet (13) exhibited activity in RCM and in ROMP of DCPD. A by-product of such activation, an aryloxybenzylidene ruthenium(Ill) complex 17 have been independently synthesised by reacting 13 with C2Cl6. This unique complex was characterised by spectroscopic and electrochemical methods, and by X-ray crystallography. To the best to our knowledge, this is the first isolated and structurally determined Ru(III) alkylidene complex reported. (C) 2018 Elsevier Inc. All rights reserved.
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