期刊
JOURNAL OF CATALYSIS
卷 361, 期 -, 页码 393-397出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2018.03.007
关键词
Amidation; C-H bond functionalization; Cobalt catalysis; Ferrocene
资金
- National Key R&D Program of China [2016YFA0202900]
- National Basic Research Program of China (973 Program) [2015CB856600]
- NSFC [21332009, 21572250]
- Strategic Priority Research Program of CAS [XDB20000000, QYZDY-SSW-SLH012]
ortho-Amidation of 2-pyridinyl ferrocenes with 1,4,2-dioxazol-5-ones was achieved via Cp*Co(III)-catalyzed direct C-H bond functionalization reaction. In the presence of Cp*Co(CO)I-2, in combination with AgPF6 and AgOPiv, a wide range of ferrocene-based amidated products were obtained in up to 96% yield under mild reaction conditions. A gram-scale reaction proceeded smoothly with high efficiency. Isoquinoline and pyrimidine are also suitable directing groups in this transformation. (C) 2018 Elsevier Inc. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据