期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 762, 期 -, 页码 301-311出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2018.05.239
关键词
Electrodeposition; Ternary nickel cobalt sulfide; N-doped porous carbon nanofibers; Supercapacitors
资金
- Collaborative Innovation Center for Modern Textile Technology of Zhejiang Province [20160202]
- 521 Talents Training Plan in Zhejiang Sci-Tech University
In this work, a novel flexible electrode material for supercapacitor is prepared by electrodeposition of NiCo-S interconnected nanosheet arrays on N-doped hierarchical porous carbon nanofibers (Ni-Co-S@NpCNIFs). The electrode exhibits a remarkable specific capacitance of 520.2 F g(-1) at the current density of 0.2 A g(-1) and 670 F g(-1) at 2 mV s(-1). The activated charcoal (AC) loaded N-doped porous carbon nanofibers (AC@N-pCNEs) as electrode is also prepared which exhibits a specific capacitance of 257.2 F g(-1) at 0.2 A g(-1), as well as excellent cycling stability with a capacitance retention of 92.6% after 5000 cycles. Furthermore, the Ni-Co-S@N-pCNEs as the positive electrode, active carbon loaded N-doped hierarchical porous carbon nanofibers (AC@N-pCNEs) as negative electrode, and KOH/NKK hybrids as both the electrolyte and separator are assembled into flexible asymmetric supercapacitor. The assembled supercapacitor device without using any current collectors or binders shows a high energy density of 21.6 Wh . kg(-1) at a power density of 134.9 W kg(-1) and robust long-term cycling stability retaining over 90.0% after 3000 cycles at 1.0 A g(-1). The as-assembled asymmetric supercapacitors (ASCs) have an outstanding mechanical flexibility and electrochemical stability and no significant attenuation occurred during cycling under different bending states. (C) 2018 Elsevier B.V. All rights reserved.
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