期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 737, 期 -, 页码 255-262出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2017.12.068
关键词
ZnFe2O4/alpha-Fe2O3; Porous structure; Sacrificial template; Heterojunction; Gas sensor
资金
- National Natural Science Foundation of China [U1404613]
- Program for Science & Technology Innovation Talents in Universities of Henan Province [18HASTIT010, 17HASTIT029]
- Young Core Instructor Project of Colleges and Universities in Henan Province [2015GGJS-063, 2016GGJS-040]
- Education Department Natural Science Foundation of fund Henan province [16A150051]
- Natural Science Foundation of Henan Province of China [162300410113]
- Fundamental Research Funds for the Universities of Henan Province [NSFRF1606, NSFRF1614]
- Foundation for Distinguished Young Scientists of Henan Polytechnic University [J2016-2, J2017-3]
Developing metal oxide nanocomposite with superior gas-sensing properties is an important subject in the field of gas sensor. In this paper, we reported a facile synthesis route for ZnFe2O4/alpha-Fe2O3 porous microrods (PMRs) by using dual oxalates as sacrificial template. FeC2O4 center dot 2H(2)O solid microrods (SMRs) were first synthesized by a chemical precipitation reaction between FeSO4 center dot 7H(2)O and H2C2O4 center dot 2H(2)O, which were then immersed in Zn2+ aqueous solution to obtain the hybrid ZnC2O4 center dot 2H(2)O/FeC2O4 center dot 2H(2)O SMRs through the substitution reaction between Zn2+ and Fe2+. After a proper annealing process, ZnFe2O4/alpha-Fe2O3 PMRs were successfully prepared through the decomposition of ZnC2O4 center dot 2H(2)O/FeC2O4 center dot 2H(2)O SMRs. The prepared ZnFe2O4/alpha-Fe2O3 PMRs are about 2-5 mu m in length and 0.3-0.5 mu m in diameter, and constructed by numerous loosely stacked nanoparticles with the size about 15 nm. The dominant pore size in ZnFe2O4/alpha-Fe2O3 PMRs is around 10 nm. The results of gas-sensing tests indicates that through decorating the alpha-Fe2O3 PMRs with ZnFe2O4, the response of the sensor towards TEA is remarkably improved. For example, the response of the composite sensor to 100 ppm TEA is as high as 42.4, which is about 20 times higher than that of the bare alpha-Fe2O3 PMRs sensor (2.5). The enhanced TEA sensing mechanism of ZnFe2O4/alpha-Fe2O3 PMRs was discussed in detail. (c) 2017 Elsevier B.V. All rights reserved.
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