期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 735, 期 -, 页码 109-116出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2017.10.264
关键词
V2O5; Hydro/solvothermal method; Yolk-shell microspheres; Cathode materials
资金
- National Natural Science Foundation of China [U1503292, 51472182]
- Fundamental Research Funds for the Central Universities
The porous V2O5 yolk-shell microspheres have been synthesized via hydro/solvothermal method with subsequent annealing treatment. Due to the volume contraction of the solid microspheres prepared by hydro/solvothermal reaction and the decomposition and combustion of the organics in air, the porous yolk-shell microspheres were prepared. Derived from the unique structure, the porous V2O5 yolk-shell microspheres show a better electrochemical performance than the pristine V2O5 powder. The electrochemical performance of yolk-shell microspheres is tested between 2.0 and 4.0 V, the V2O5 microspheres can deliver a high initial capacity of 287.2 mA h g(1), and a good capacity of 225.7 mA h(-1) can be reached at a current density of 50 mA g(-1) after 50 cycles. Moreover, the microspheres electrode possess a higher capacity than the pristine V2O5 powder under the same rate, for example, 159.5 mA h g(-1) of V2O5 yolkshell microspheres vs. 144.6 mA h g(1) of pristine V2O5 powder at a current density of 2000 mA g(-1). Even at 1000 mA g(-1) in the voltage range of 2.5-4.0 V, the yolk-shell microspheres can also deliver a good discharge capacity of 117.5 mA h g(-1) after 1000 cycles. (C) 2017 Elsevier B.V. All rights reserved.
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