期刊
ISRAEL JOURNAL OF CHEMISTRY
卷 58, 期 5, 页码 586-595出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.201700074
关键词
propargyl acetate; gold catalysis; total synthesis; organogold intermediate; acetate migration
资金
- UPMC
- CNRS
- ANR
- IUF
Gold catalysis has emerged over the last two decades as a protocole of choice for the efficient and selective activation of a variety of organic functional groups. This has served to the total synthesis of natural products at several occasions. In this context, the gold-catalyzed migration (1,2- or 1,3-) of propargyl acetates has been particularly used. This review highlights these different synthetic developments which are presented according to the involved mechanisms.
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