期刊
IONICS
卷 24, 期 10, 页码 2957-2963出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s11581-018-2467-9
关键词
Lithium-ion battery; LiNi0.5Co0.2Mn0.3O2; Lithiated precursor; High-temperature crystallization; Electrochemical properties
资金
- Glorious Laurel Scholar Program of the Government of Guangxi Zhuang Autonomous Region [2011A025]
The lithiated transition metal oxide precursor (LNCMO) with typical alpha-NaFeO2 structure and imperfect crystallinity, obtained from a hydrothermal process, was pretreated at 500 A degrees C and then subjected to sintering at 800-920 A degrees C to synthesize the ternary layered LiNi0.5Co0.2Mn0.3O2 (NCM523). X-ray diffraction (XRD), scanning electron microscope (SEM), cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and charge/discharge testing were used for investigating the effect of the high-temperature crystallization on the properties of the NCM523 cathode materials. The results show that the materials heated at 880-900 A degrees C possess superior cation ordering, perfect crystallinity, and excellent electrochemical performances, among which the material heated at 900 A degrees C delivers better performances, with the initial discharge capacity of 152.6 mAh g(-1) at 0.5 C over 3.0 to 4.3 V and the capacity retention of 95.5% after 50 cycles. Furthermore, the effect of the high-temperature crystallization on the Li+ diffusion coefficient, potential polarization, and electrochemical resistance are discussed.
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