期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 43, 期 22, 页码 10502-10510出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2018.04.134
关键词
Polyaniline; Spherical ordered mesoporous carbon; Electrochemical performance; Lithium-sulfur battery
资金
- National Natural Science Foundation of China [51572012]
- Doctoral Fund of Ministry of Education of China [20120010110001]
Lithium-sulfur batteries have attracted a lot of attention in the recent years. However, the electrochemical performance of lithium-sulfur batteries is greatly affected owing to several issues. In this paper, we designed a polyaniline@spherical ordered mesoporous carbon/sulfur nanocomposite (PANI@S-OMC/S), and S-OMC/S was wrapped by PANI via in-situ polymerization. The inherently conducting nature of PANI increased conductivity of PANI@S-OMC/S electrode to improve the free transfer of electrons, and PANI shell also provided a barrier between the lithium polysulfides and electrolyte to further prevent the occurrence of the shuttle effect. Moreover, mesoporous pores are wonderful hosts to contain sulfur to trap the long-chain lithium polysulfides and prevent them from dissolving in electrolyte. A high initial discharge capacity of 1626 mAh/g was achieved for the PANI S-OMC/S electrode in first cycle at 0.1 C, and the composite maintains 1338 mAh/g after 100 cycles while the coulombic efficiency still remains-98%. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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