期刊
INORGANICA CHIMICA ACTA
卷 470, 期 -, 页码 106-112出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2017.04.044
关键词
Dendrimers; Complexes; PTA phosphine; Homogeneous catalysis; DNA interaction
资金
- CNRS (France)
- EU COST [CM1302 SIPs]
Phosphorhydrazone dendrimers ended by PTA (1,3,5-triaza-7-phosphaadamantane) derivatives are used for the complexation of ruthenium. The corresponding complexes, either isolated (synthesized ex situ, i.e. preformed) or generated in situ are used as catalysts for the hydration of phenylacetylene in various conditions (ex situ or in situ, quantities, temperature, duration, co-catalyst or not, recycling). The same preformed complexes are tested for their interaction with supercoiled DNA, to afford relaxed DNA. (C) 2017 Elsevier B.V. All rights reserved.
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