期刊
INORGANICA CHIMICA ACTA
卷 479, 期 -, 页码 165-171出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2018.04.037
关键词
Metal-organic framework; Structure; Strecker reactions; Catalyst
资金
- National Natural Science Foundation of China [21171065, 21201077, 21401005]
A novel three-dimensional metal-organic framework (MOF) {[In3(NIPH)(3) (HNIPH)(OH)(2)].4H(2)O}(n) (1) (H2NIPH = 5-nitroisophthalic acid) with one-dimensional channels was synthesized and structurally characterized. Importantly, it demonstrates excellent catalytic activity for the Strecker reactions of two or three components under mild conditions. Moreover, the catalytic recycling of 1 as a representative example was explored. It can be easily separated and reused for no less than five runs with more than 80% conversion yield in catalytic ability.
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