期刊
INORGANIC CHEMISTRY
卷 57, 期 5, 页码 2678-2685出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b03077
关键词
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资金
- Taishan scholar's construction project
- NSFC [21501111, 21475078, 21301109, 21671122]
Condensation of benzene-1,3,5-tricarbohydrazide with benzene-1,4-dicarboxaldehyde generated a new covalent organic framework, COF-ASB (1), in which the organic units are held together via hydrazone linkage to form porous frameworks. COF-ASB (1) is highly crystalline and displays good chemical and thermal stability and is permanently porous. In addition, 1 can be an ideal support to load Ru nanoparticles (Ru NPs) to generate Ru@COF-ASB (2). The obtained composite material is able to highly promote one-pot tandem synthesis of imine products from benzyl alcohols and corresponding amines under solvent-free conditions in air.
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