Photophysics and Photoredox Catalysis of a Homoleptic Rhenium(I) Tris(diisocyanide) Complex

Herein a homoleptic rhenium(I) complex bearing three chelating diisocyanide ligands and its photophysical properties are communicated. The complex emits weakly from a high-energy triplet metal-to-ligand charge-transfer excited state with an 8 ns lifetime in deaerated CH3CN at 22 degrees C and is shown to act as an efficient photoredox catalyst comparable to [Ir(ppy)(3)] (ppy = 2-phenylpyridine) in representative test reactions.