期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 57, 期 14, 页码 4949-4954出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.8b00094
关键词
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资金
- Foundation of Key Laboratory of Clay Mineral Applied Research of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences [CMAR-03]
A versatile approach was developed for the preparation of cross-linked attapulgite (ATP)-nitrile butadiene rubber (NBR) nanocomposites or NBR grafted ATP nanorods, by facilely adjusting the feeding ratio between the butadiene-based rubbers and the thiol-modified attapulgite (ATP-SH) nanorods in a facile thermal-triggered thiol-ene interfacial dick reaction. The modified products with different feeding ratios between the ATP-SH and NBR were characterized with FT-IR, TGA, and TEM techniques. The results indicated that the cross-linked ATP-NBR nanocomposites could be produced via the thiol-ene interfacial click reaction with excess NBR, while the NBR grafted ATP nanorods could be synthesized via the reaction with excess ATP-SH nanorods. Based on the results, a possible mechanism and potential applications were proposed.
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