期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 57, 期 14, 页码 4848-4858出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.8b00511
关键词
-
资金
- Ministry of Science and Technology of the Republic of China [MOST 105-3113-E-009-003]
The MnFe/TiO2 catalysts were poisoned by metal sulfates and/or ammonium sulfate to understand the SO2 poisoning effect under low-temperature selective catalytic reduction (SCR) of NO with NH3. The results showed that the formation of metal sulfates had a more serious deactivation effect than that of ammonium salts on the MnFe/TiO2 catalysts. After thermal regeneration, the metal sulfates on the catalyst could not be removed so that the NOx conversion was only recovered from 17% to 35%. On the other hand, water washing was capable to remove both ammonium salts and metal sulfates, and the NOx conversion could be recovered to 88% (compared to 99% for the fresh catalyst). The analytical results of the synchrotron-based XRD, BET, NH3-TPD, and XPS revealed that lower crystallinity, lower specific surface area, lower ratio of Mn4+/Mn3+, higher surface acidity, and more chemisorbed oxygen were the main causes for the presence of metal sulfates poisoning, which then resulted in the low NOx conversion at low temperature.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据