4.6 Review

Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries

期刊

RSC ADVANCES
卷 5, 期 4, 页码 2732-2748

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra11575a

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资金

  1. IT R & D program of MKE/KEIT [KI001810039182]
  2. Energy Efficiency & Resources of the Korea Institute of Energy Technology Evaluation and Planning - Korean Ministry of Knowledge Economy [20112010100140]
  3. National Research Foundation of Korea - Korean Government (MEST) [NRF-2013-C1AAA001-0030538]
  4. Korea Evaluation Institute of Industrial Technology (KEIT) [20112010100140] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  5. National Research Foundation of Korea [2011-0030544] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Advanced electrolytes with unique functions such as in situ formation of a stable artificial solid electrolyte interphase (SEI) layer on the anode and the cathode, and the improvement in oxidation stability of the electrolyte have recently gained recognition as a promising means for highly reliable lithium-ion batteries with high energy density. In this review, we describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganese oxide (NCM), spinel lithium manganese nickel oxide (LNMO), and lithium-rich layered oxide (Li-rich cathode))electrolyte interfaces and highlight the recent progress in the use of oxidative additives and high-voltage solvents in high-performance cells.

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