期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 17, 期 17, 页码 11586-11592出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cp01307k
关键词
-
资金
- ERC [279705]
- EPSRC [EP/G004528/2]
- GENCI-IDRIS [x2015087069]
- EPSRC [EP/G004528/2] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G004528/2] Funding Source: researchfish
Thermally-densified hafnium terephthalate UiO-66(Hf) is shown to exhibit the strongest isotropic negative thermal expansion (NTE) effect yet reported for a metal-organic framework (MOF). Incorporation of correlated vacancy defects within the framework affects both the extent of thermal densification and the magnitude of NTE observed in the densified product. We thus demonstrate that defect inclusion can be used to tune systematically the physical behaviour of a MOF.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据