期刊
RSC ADVANCES
卷 5, 期 25, 页码 19601-19612出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra01876e
关键词
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资金
- National Natural Science Foundation of China [51179033, 21476053]
- Doctoral Program of the Ministry of Education [20132304110027]
- Fundamental Research Funds for the Central Universities [HEUCF201403019]
- Heilongjiang Postdoctoral Science Research Foundation [LBH-Q12118]
- Special Fund Research Program for Talents of Science Technology Innovation in Harbin [2009RFXXG204]
Sb-doped SnO2 electrode was fabricated by the one-step pulse electro-codeposition method, and was modified through either cerium dioxide nanoparticle (nano-CeO2) or cerium ion doping. The results showed that the effects of nano-CeO2 doping and cerium ion doping are quite different. Nano-CeO2 doping shrinks the unit cell volume, improves the degree of crystallinity and refines crystalline grains, while cerium ion doping expands the volume and deteriorates the crystallinity. Nano-CeO2 doping mitigates the surface antimony enrichment and promotes the complete oxidation of antimony so that the majority of antimony oxidation states exist as the Sb5+ state, but cerium ion doping aggravates the enrichment and increases the Sb3+ content. Electrochemical phenol degradation showed that the Ti/Sb-SnO2-CeO2 electrode has a higher degradation efficiency and its kinetic rate constant is 1.46 times as much as that of Ti/Ce-Sb-SnO2. Besides, due to the compact active layer of Ti/Sb-SnO2-CeO2 protecting the titanium substrate from passivation, the accelerated service lifetime of Ti/Sb-SnO2-CeO2 is prolonged, which is 1.28 times as long as that of Ti/Ce-Sb-SnO2.
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