期刊
JOURNAL OF ASIAN CERAMIC SOCIETIES
卷 3, 期 1, 页码 92-102出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jascer.2014.11.004
关键词
Mechanical properties; Calcium aluminate; Synthesis; Refractories
High-energy ball milling viz. mechanochemical process is being utilized to mechanically activate ceramic powders for low temperature solid state reactions. The process can help to select low-cost commercially available oxides and can produce powders with nanometer size granules. On the other hand, high alumina cement provides high service temperature when used as refractory castable. Therefore, the effects of highenergy ball milling and subsequent calcinations on the formation of high alumina cementing phases using mixtures of Al2O3 and CaCO3 were investigated. Nano-meter sized high alumina cement (HAC) powders were synthesized by mechanochemical treatment of Al2O3 and CaCO3 in weight ratios 7:3 and 8:2. This paper compares the calcined high alumina cement obtained by mechanically activated precursor mix for 1, 2 and 3 h. Low cement castables were prepared from calcined Chinese bauxite as aggregate matrix, prepared HAC acting as hydraulic binder and micro-fine additives as pore filling agents. The bonding of high alumina cement as well as sinterability in these castable was studied with ZrO2, alpha-Al2O3 and SiC as micro-fine additives. Castables formulated by prepared high alumina cement demonstrate remarkably improved bulk density and apparent porosity as when compared with those prepared by commercially available cement. Casting water demand was also reduced, as a result quick setting behavior was observed. The addition of mechanochemically processed cements in refractory castables improved the thermo-mechanical properties to a significant extent. (C) 2014 The Ceramic Society of Japan and the Korean Ceramic Society. Production and hosting by Elsevier B.V. All rights reserved.
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