期刊
HETEROCYCLES
卷 97, 期 2, 页码 712-718出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-18-S(T)71
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资金
- JSPS KAKENHI [JP22390002, JP24106731, JP16H01157, JP26293004, JP17K14449]
- Science and Technology Research Promotion Program for Agriculture, Forestry, Fisheries and Food industry
- MEXT Project of Integrated Research Consortium on Chemical Sciences
- Grants-in-Aid for Scientific Research [17K14449] Funding Source: KAKEN
The first asymmetric total synthesis of (-)-isostemonamine is reported herein. The key reactions include the regioselective oxidation of the diketone, which is reported to be an intermediate in our synthesis of (-)-stemonamine. The chiral high-performance liquid chromatography (HPLC) analysis of the racemization and epimerization of (-)-isostemonamine revealed that isostemonamine isomerizes significantly faster than stemonamine.
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