期刊
GREEN CHEMISTRY
卷 20, 期 9, 页码 1981-1986出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc03743k
关键词
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资金
- CEA
- CNRS
- CHARMMMAT Laboratory of Excellence
- European Research Council (ERC) [336467]
- Fondation Louis D. - Institut de France
- CINES [c2017086494]
Efficient catalytic reduction of lignin model molecules and reductive depolymerization of softwood and hardwood lignins is presented with the iridium based Brookhart's catalyst and hydrosilanes R3SiH as reductant. This catalyst displays increased stability and selectivity in comparison to the B(C6F5)(3)/hydrosilane system and it enables a convergent reductive depolymerization of wood lignins to isolable mono-aromatics.
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