期刊
GREEN CHEMISTRY
卷 20, 期 6, 页码 1362-1366出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc03392c
关键词
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资金
- Fundamental Research Funds for the Central Universities [020514380114]
- National Natural Science Foundation of China [21332005, 21472085]
An effective and operationally simple protocol is reported for the synthesis of versatile carbazoles. With water as a co-solvent, visible-light rather than various metals is used to facilitate the conversion of readily available 2-azidobiphenyls under mild conditions. Various functionalized bioactive natural alkaloids, such as glycoborine, clausine C, clausine L, clausine H and clauszoline K, were synthesized efficiently with nitrogen as a sole byproduct. The reaction could be performed in water, acidic or alkaline buffer solutions, showing its potential for applications in biochemistry.
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