期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 98, 期 4, 页码 1372-1376出版社
WILEY-BLACKWELL
DOI: 10.1111/jace.13461
关键词
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资金
- NSF of China [11204313, 11274287, 11205235, 51332002]
- National Basic Research Program of China [2012CB927402, 2010CB934501]
- Tsinghua University Initiative Scientific Research Program [20131089230]
The phase transition temperatures of CaZrO3-doped (Na0.49K0.49Li0.02)(Nb0.8Ta0.2)O-3 lead-free piezoelectrics (LKNNT-CZ5) have been studied with X-ray diffraction and Raman scattering. It is found that LKNNT-CZ5 ceramics and powders with the same crystallite size (similar to 2-5m) exhibit distinctly different phase transition behaviors versus temperature. The ceramic bulk changes its orthorhombic phase to tetragonal structure abruptly after being pulverized to powders at room temperature(RT), and follows a phase transition sequence with increasing temperature: orthorhombic (RT-65 degrees C), orthorhombic and tetragonal (65 degrees C-105 degrees C), and tetragonal phase (105 degrees C to similar to 220 degrees C). Contrastively, the powders hold a tetragonal structure without any phase transition within the whole temperature region (RT-220 degrees C). These differences might be induced by the existing internal stress or residual strain, which could be released during the grinding process.
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