期刊
RSC ADVANCES
卷 5, 期 33, 页码 26097-26106出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra02468d
关键词
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资金
- Dalhousie University
- Canada Research Chairs Program
- Natural Science and Engineering Council of Canada (NSERC) [EGP 453320-2013]
The commercially available silica-supported heterogeneous catalyst SiliaCat (R) DPP-Pd has proven to be highly active, robust, and reusable for the synthesis of a thiophene-phthalimide-based molecular semiconductor under microwave-irradiation reaction conditions. A Stille reaction protocol demonstrated that SiliaCat (R) DPP-Pd outperformed well-known homogeneous catalysts, Pd(PPh3)(4) and Pd(PPh3)(2)Cl-2, in terms of performance and catalyst loading, while also exhibiting tolerance to ambient reaction conditions and two-fold recyclability for the formation of product. The success established for SiliaCat (R) DPP-Pd catalyzed Stille reactions via microwave irradiation was extended to optimize Suzuki coupling and direct heteroarylation protocols. Notably, direct heteroarylation with SiliaCat (R) DPP-Pd exhibited excellent selectivity and perturbed the formation of homo-coupled aryl bromides, two side reactions that are known to plague this type of cross-coupling reaction.
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