期刊
RSC ADVANCES
卷 5, 期 34, 页码 26863-26871出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra03645c
关键词
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资金
- National Basic Research Program of China (973 Project of China) [2011CB935901]
- National Natural Science Fund of China [21371108]
- Shandong Provincial Natural Science Foundation for Distinguished Young Scholar [JQ201304]
- National Science Foundation of Shandong Province [ZR2012BM018]
In this investigation, we designed a general method to manipulate the controlled preparation of Mn-based transition metal oxide materials with the structure of hierarchical twin-microspheres. Initiated by a precursor solvothermal synthesis of metal carbonate twin-microspheres, the formation of hierarchical twin-microspheres of metal oxides was finalized by thermal annealing in laboratory air. The method allows one to prepare binary and ternary hierarchical twin-microspheres constructed by primary ultrathin nanoparticles. By applying the respective metal salts in the synthesis, six oxide species, including Mn3O4, CoMn2O4, ZnMn2O4, NixMn3-xO4, CuxMn3-xO4, and FexMn3-xO4, have been reported herein in order to draw common features via oriented-attachment. Concerning the workability, CoMn2O4 twin-microspheres are evaluated as electrode materials for lithium-ion batteries. As expected, the CoMn2O4 twin-microspheres exhibit excellent rate performance and impressive cycling stability due to their unique assembled architecture and probably synergetic effects of different metal ions.
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