期刊
FUEL
卷 216, 期 -, 页码 747-751出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2017.12.062
关键词
gamma-Valerolactone; Hydrocarbon oil; Deoxygenation; Phosphoric acid catalyst
资金
- National Natural Science Foundation of China [21606045]
- Natural Science Foundation of Guangdong Province of China [2017A030313084]
Catalytic reforming reaction of gamma-valerolactone (GVL) derived from renewable cellulosic biomass was conducted to produce hydrocarbon oils using a phosphoric acid catalyst under mild temperature (240 degrees C). Excellent catalytic performance (over 99% conversion of GVL, 33.5 wt% yield of hydrocarbon oils) was achieved in a one-step reaction without external source of hydrogen. The hydrocarbon oil formed was rich in aromatics and had similar C/H ratio and higher heating value (HHV) in comparison with oxygenated commercial gasoline.
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