期刊
FOOD HYDROCOLLOIDS
卷 85, 期 -, 页码 61-68出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.foodhyd.2018.07.002
关键词
Film; kappa-Carrageenan; Hydroxypropyl methylcellulose; Rheological behaviors; Physical properties
资金
- National Natural Science Foundation of China [31770618]
- Fundamental Funds for Central Universities [E2572017EB05]
Flexible hydrogel films based on kappa-carrageenan and hydroxypropyl methylcellulose (HPMC) were prepared. The effects of glycerol, sorbitol and PEG-400 on the film properties were studied. There was a good miscibility between kappa-carrageenan and HPMC. With an increase in plasticizer content, the tensile strength and light transmittance of the film decreased, and the elongation at break, oxygen permeability, swelling ratio and film flexibility increased. The Fourier transform infrared spectroscopy, rheological and X-ray diffraction results indicated that the plasticizers formed new hydrogen bonds and had a disorderly restructuring with the kappa-carrageenan and HPMC. Glycerol affected the properties of the kappa-carrageenan/HPMC (CH) film to a greater extent than sorbitol and PEG-400. When the addition increased from 40% to 60%, the tensile strength decreased 24.22%, 18.23% and 12.80% and the oxygen permeability increased 10.72%, 23.92% and 47.49% for films plasticized with glycerol, sorbitol and PEG-400, respectively. Sorbitol-plasticized films showed an excellent strength, oxygen barrier, light transmission and thermal stability. Scanning electron microscopy showed that the increasing plasticizer addition made the bulk of the hydrogel films more uniform and compact. This study indicates that sorbitol-plasticized CH hydrogel film has potential for application in packaging, cosmetics and other industries.
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