期刊
FOOD CHEMISTRY
卷 245, 期 -, 页码 768-774出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.foodchem.2017.11.113
关键词
Modified mycotoxins; Drift-time ion mobility mass spectrometry; Metabolite structural characterization
资金
- Czech Science Foundation (GACR) [16-06008S]
- Operational Programme Prague - Competitiveness [CZ.2.16/3.1.00/21537, CZ.2.16/3.1.00/24503]
- National Programme of Sustainability I - NPU I [LO1601, MSMT-43760/2015]
This work was designed as a proof of concept, to demonstrate the successful use of the comparison between theoretical and experimental collision cross section (CCS) values to support the identification of isomeric forms. To this purpose, thirteen mycotoxins were considered and analyzed using drift time ion mobility mass spectrometry. A good linear correlation (r(2) = 0.962) between theoretical and experimental CCS was found. The average Delta CCS was 3.2%, fully consistent with the acceptability threshold value commonly set at 5%. The agreement between theoretical and experimental CCS obtained for mycotoxin glucuronides suggested the potential of the CCS matching in supporting the annotation procedure.
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