期刊
EUROPEAN POLYMER JOURNAL
卷 105, 期 -, 页码 167-176出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2018.05.037
关键词
Thermosetting resins; Adhesion; Toughness; Mechanical properties; DMA
资金
- EuroResinas - Industrias Quimicas S.A.
- Project 2GAR (SI I&DT - Projects in co-promotion) - FEDER (Fundo Europeu de Desenvolvimento Regional)
- FEDER funds through COMPETE2020 - Programa Operacional Competitividade e Inteniacionalizacao (POCI) [POCI-01-0145-FEDER-006939]
- FCT Fundacao para a Ciencia e a Tecnologia [POCI-01-0145-FEDER-006939]
- Project CICECO-Aveiro Institute of Materials
- FCT/MEC [POCI-01-0145-FEDER-007679, UID/CTM /50011/2013]
- FEDER
- FCT [PD/BDE/113544/2015]
Urea-formaldehyde resins are successfully used in many contexts, but their tightly crosslinked thermoset structure impairs some applications, due to stiff and brittle behavior. In this work we show that copolymerization of urea and formaldehyde with glycols introduces linear flexible segments in the polymer structure, thus increasing the resilience and flexibility of the resin after curing. Glycols with different molecular weights (106, 200 and 400 g/mol) were incorporated in the synthesis in different amounts. The chemical and physical-mechanical properties of the resulting products were investigated in detail, namely using FTIR, C-13 RMN, GPC/SEC analysis, dynamic mechanical analysis, adhesive bond strength, and tensile-strain testing. Use of polyethyleneglycol with molecular weight 200 g/mol yielded the most promising glycol-urea-formaldehyde resin, with remarkable resilience and good adhesion properties. When used for paper impregnation, the modified resins yielded flexible and tough papers, in comparison with a conventional urea-formaldehyde resin, which produced brittle papers that fractured easily upon bending.
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