期刊
RSC ADVANCES
卷 5, 期 55, 页码 44642-44647出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra05554g
关键词
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资金
- National Natural Science Foundation of China [21171035, 51472049, 51302035]
- Key Grant Project of Chinese Ministry of Education [313015]
- PhD Programs Foundation of the Ministry of Education of China [20110075110008, 20130075120001]
- National 863 Program of China [2013AA031903]
- Science and Technology Commission of Shanghai Municipality [13ZR1451200]
- Fundamental Research Funds for the Central Universities
- Shanghai Leading Academic Discipline Project [B603]
- Program of Introducing Talents of Discipline to Universities [111-2-04]
- Program Innovative Research Team in University [IRT1221]
We report on the development of 3D hierarchical NiCo2S4@MnO2 core-shell nanosheet arrays on Ni foam for supercapacitors. In our design, the highly conductive NiCo2S4 nanosheets can serve not only as a good pseudocapacitive material, which can be contributed to the capacitance of the whole electrode, but also as a 3D conductive scaffold for loading MnO2 materials, which can overcome the limited conductivity of MnO2 itself. Furthermore, the 3D NiCo2S4@MnO2 hybrid electrode can provide efficient and rapid pathways for ion and electron transport. These merits together with the elegant synergy between NiCo2S4 and MnO2 lead to a high areal capacitance of 2.6 F cm(-2) at 3 mA cm(-2) and good cyclic stability.
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