期刊
FUEL PROCESSING TECHNOLOGY
卷 137, 期 -, 页码 204-211出版社
ELSEVIER
DOI: 10.1016/j.fuproc.2015.04.022
关键词
Bimetallic catalyst; CO2 methanation; ZrO2 support; Low-temperature activity
资金
- National Natural Science Foundation of China [21376159, 21276169]
- National Science Foundation for Post-doctoral Scientists of China [2014M551060]
- Key Science and Technology Program of Shanxi Province [20120313005-1]
- Natural Science Foundation of Shanxi Province [2013011042-2]
Ni/ZrO2 catalysts with an added second metal were prepared by impregnation method and used in CO2 methanation. X-ray diffraction, hydrogen temperature programmed reduction, hydrogen temperature programmed desorption, X-ray photoelectron spectroscopy, and in situ infrared spectroscopy measurements were taken to characterize the surface and bulk properties of the catalysts. Compared with Co and Cu, Fe could efficiently enhance the catalytic activity of Ni/ZrO2 in CO2 methanation at low temperatures. The optimal amount of Fe was 3 wt.%. CO2 methanation over Ni-Fe/ZrO2 catalysts may proceed through dissociation of CO2 into CO and subsequent reaction of CO with hydrogen to generate methane. Addition of Fe not only can improve the dispersion and degree of reduction of Ni, but also can enhance the partial reduction of zirconia. These effects further promote adsorption and dissociation of H-2 and CO2, thus enhancing the activity of the catalyst in CO2 methanation. (C) 2015 Elsevier B.V. All rights reserved.
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