期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2018, 期 20-21, 页码 2609-2614出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201800111
关键词
Chiral sulfinyl imines; Heck reaction; Homogeneous catalysis; One-pot process; Isomerization; Sulfinamides
资金
- Ministerio de Ciencia e Innovacion (MCINN
- projects CONSOLIDER INGENIO) [2010-CDS2007-00006, CTQ2011-24165]
- Ministerio de Economia y Competitividad (MINECO) [CTQ2014-53695-P, CTQ2014-51912-REDC, CTQ2016-81797-REDC, CTQ2017-85093-P]
- FEDER
- Generalitat Valenciana [PROMETEO 2009/039, PROMETEOII/2014/017]
- University of Alicante
- Ministere de l'Enseignement Superieur et de la Recherche Scientifique Algerienne
- Direction de la Cooperation et des Echanges Interuniversitaires
- Programme de Formation Residentielle a l'Etranger au titre de l'annee universitaire: Programme National Exceptionnel (PNE)
The reaction of aryl iodides, N-tert-butanesulfinamide, and allyl or homoallyl alcohol in the presence of a catalytic amount of Pd(OAc)(2), NaHCO3 as a base, and TBAB leads to the formation of N-tert-butanesulfinyl imines in moderate yields. In this one-pot process, a sequential Heck-type arylation of the alkenol, isomerization of the double bond, and imine formation take place.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
