期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2018, 期 3, 页码 418-421出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201701699
关键词
Cyclopropanation; Fluorine; Ylides; Diastereomers; Synthetic methods
资金
- Austrian Science Funds (FWF) [P26387-N28]
- European Union through the EFRE INTERREG IV ETC-AT-CZ program [M00146]
- Austrian Science Fund (FWF) [P26387] Funding Source: Austrian Science Fund (FWF)
The use of carbonyl-stabilized ammonium- and sulfonium ylides allows for the synthesis of highly-functionalized trifluoroacetyl-substituted cyclopropanes. It turned out that the diastereoselectivities strongly depend on the nature of the chosen ylide and the employed base. The products could be obtained in good yields under operationally simple conditions.
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