期刊
FUEL PROCESSING TECHNOLOGY
卷 138, 期 -, 页码 125-132出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.fuproc.2015.04.029
关键词
Lignite; Thermal dissolution; Cyclohexane; Hydrocarbons; Intermolecular interactions
资金
- National Basic Research Program of China [2011CB201302]
- Natural Science Foundation of China for Innovative Research Group [51221462]
- National Natural Science Foundation of China [51074153, 21206187, 21206188, 51134021]
- Shenhua Group Corporation Limited [51134021]
- Strategic Chinese-Japanese Joint Research Program [2013DFG60060]
- Fundamental Research Fund for the Central Universities (China University of Mining Technology) [2014QNA83]
- China Postdoctoral Science Foundation [2014M561730]
- Jiangsu Postdoctoral Science Foundation [1401098C]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
Xianfeng lignite (XL) was subjected to sequential thermal dissolution (TD) in cydohexane at 200-320 degrees C. The yields of soluble portions (SPs) decreased with raisins temperature from 200 to 260 degrees C, but then increased with further raising the temperature. The SPs were analyzed with a Fourier transform infrared spectrometer, gas chromatograph/mass spectrometer, and atmospheric pressure solid analysis probe/time-of-flight mass spectrometer (ASAP/TOF-MS). The results show that cyclohexane is effective for thermally extracting inherent hydrocarbons in XL without breaking the covalent bonds. Intermolecular interactions such as hydrogen bonds, pi-hydrogen bonds, and pi-pi interactions can be destroyed at higher temperatures and thereby release arenes and arenols trapped in the capsule structure of XL. According to ASAP/TOF-MS analysis, the molecular mass of organic species in the SPs is smaller than 550 u and SPs from different TO temperatures have different molecular mass distributions. The organic species detected with ASAP/TOF-MS have double bond equivalent values ranging from 0 to 11 and carbon numbers from 3 to 35. A series of arenes and alkylarenols were also confirmed by ASAP/TOF-MS analysis. (C) 2015 Elsevier B.V. All rights reserved.
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