期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 25, 页码 2944-2951出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201800423
关键词
Oxidation; Surface oxygen vacancies; Bulk oxygen vacancies; Cerium; Silver
资金
- National Engineering Laboratory for Carbon Fiber Technology of Institute of Coal Chemistry of Chinese Academy of Sciences
Three types of CeO2 were synthesized and through impregnation of Ag employing these CeO2 types as supports, three kinds of Ag/CeO2 were prepared. Their morphologies and structures were characterized by SEM, HRTEM, nitrogen adsorption-desorption isotherms, and H-2-TPR reduction, indicating that the effective soot-catalyst contact and size distribution as well as the chemical state of Ag were identical. Surface oxygen vacancies (VO-s) and bulk oxygen vacancies (VO-b) were investigated by using XPS and Raman spectroscopy, respectively. The activities of the CeO2 catalysts are related to surface chemisorbed oxygen, while the activities of Ag/CeO2 are decided by VO-s near the Ag particles under oxygen-rich conditions. When switching the atmosphere to oxygen-poor conditions, the activities of Ag/CeO2 are controlled by VO-b instead. These results originate from the fact that the generation and delivery of active oxygen are affected by combinations of VO-s and VO-b rather than just one of them. The moderate concentration of VO-s and sufficient concentration of VO-b are favorable for increasing catalytic activity under oxygen-poor conditions for Ag/CeO2. In this work, Ag loaded on CeO2, prepared at 50 degrees C, (defined as Ag/CeO2-50) can be considered as a prospective catalyst for use in gasoline particulate filters.
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