期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 16, 页码 1766-1774出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201800251
关键词
Metathesis; Ruthenium; Polymerization; Homogeneous catalysis; Carbene ligands
资金
- National Science Centre (Poland) [DEC-2012/04/A/ST5/00594]
- European Union from the European Regional Development Fund under the Operational Programme Innovative Economy
A set of olefin metathesis catalysts bearing a ruthenium amide moiety was synthesised. In the ruthenium amide form these complexes exhibit very low activity in standard metathesis reactions. However, a dramatic increase of activity was observed upon in situ activation with trimethylsilyl chloride or HCl, allowing successful application of such catalysts in a number of model ring-closing metathesis, cross-metathesis and enyne transformations. Moreover, such activated complexes proved to be very effective catalysts for bulk polymerisation of dicyclopentadiene (DCPD). The influence of factors such as temperature and the nature of additives on the properties of poly-DCPD was examined.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据