期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 24, 页码 2734-2754出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201800459
关键词
Carbene ligands; Phosphinidenes; Main group elements; Adducts; Phosphinidene transfer
资金
- European Union (Marie Curie ITN SusPhos) [317404]
- Council for Chemical Sciences of The Netherlands Organization for Scientific Research (NWO/CW) by a VIDI grant
Syntheses, properties, and reactivity of N-heterocyclic carbene-phosphinidene adducts are reviewed. These adducts, formally built by combining a phosphinidene with a carbene, are characterized by high nucleophilicity at the phosphorus atom. The main types of reactivity these adducts exhibit are: Lewis-base reactivity towards main group and organic compounds as well as transition-metal complexes, substitution reactions at the phosphorus atom with main group compounds and transition-metal complexes, and phosphinidene transfer reactions resulting in C-P bond cleavage. These differ substantially from the classic phosphaalkenes.
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