期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 29, 页码 3433-3438出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201800311
关键词
Cobalt; Reduced graphene oxide; Batteries; Nanoparticles; Electrochemistry
资金
- National Natural Science Foundation of China [51702228, 21575099]
- Natural Science Foundation of Shandong Province [ZR2017BEM014, ZR2017BB050]
- Shandong Province Higher Educational Science and Technology Program [J17KA023]
- China Postdoctoral Science Foundation [2018M630792]
- Talent Introduction Project of Taishan University [Y-01-2016004]
- Shandong Province Science and Technology Program [2014GGX102020]
Cobalt phosphide/reduced graphene oxide (CoP/RGO) nanohybrid materials have been prepared by a simple chemical precipitation method and a low-temperature phosphorization process. Ultrafine CoP nanoparticles are loaded uniformly onto RGO nanosheets. The diameter of the CoP particle decreases to about 6-8 nm. Sodium ion battery anodes based on the CoP/RGO nanohybrids display significantly improved sodium ion storage performance. These electrode materials demonstrate a large capacity of about 490 mAhg(-1), at a current density of 100 mAg(-1), after 100 cycles. They also deliver good rate performance, demonstrating about 381 mAhg(-1) specific capacity when the current density reaches 2.0 Ag-1. The ultrafine nanoparticles, interconnected porous structure, large surface area, and good electrical conductivity are the major reasons for the excellent electrochemical performance. The synthesis method presented here is general, easy, and efficient, and can be developed for other metal phosphide-graphene composites.
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