期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 2, 页码 203-207出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201701494
关键词
Porphyrinoids; Pentadentate ligands; Homogeneous catalysis; Cobalt; Ruthenium
资金
- JSPS KAKENHI [JP15K13646, JP16K05700, JP17H05377]
- JSPS
- National Research Foundation (NRF) of South Africa
- Grants-in-Aid for Scientific Research [16K05700] Funding Source: KAKEN
Bioinspired pentadentate ligand N-confused porphyrin (NCP) bearing a 2-mercaptopyridine group and its Ru-II and Co-III complexes were synthesized. Their structures were revealed by single-crystal X-ray crystallographic analysis. Installation of an axial thiopyridine ligand shifts the redox potentials negatively and enhances the catalytic activity largely, which was demonstrated in the cyclopropanation reaction using the Co complex.
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