期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 22, 页码 2541-2548出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201800283
关键词
Heteroacene; Pyrazinacene; Tautomerization; Phenanthroline; Dye-sensitized solar cells
资金
- National Science Foundation [1401188]
- Grant Agency of Charles University (project GA UK) [718214]
- JSPS KAKENHI [JP15K13684, JP16H06518]
- CREST JST, Japan [JPMJCR1665]
- World Premier International Research Center Initiative (WPI Initiative), MEXT, Japan
- Grants-in-Aid for Scientific Research [15K13684] Funding Source: KAKEN
We report the one-pot synthesis of a phenanthroline-fused pyrazinacene derivative (6,13-dihydrodipyrido[3,2-a:2,3-c]-5,6,7,8,11,12,13,14-octaazapentacene-9,10-dicarbonitrile) and its behaviour under alkylating conditions used to improve solubility. Tautomerization of the starting pyrazinacene due to the presence of a reduced pyrazine ring contained within an octaazatetracene chromophore led to mixtures of isomers, and factors affecting the relative yields of these isomers were considered. Isomer population can be described by a two-step reaction model where initial N-alkylation affects the reactivity of the remaining nitrogen atoms available for subsequent alkylation. A discrete soluble non-isomerizable phenanthroline-fused pyrazinacene was also prepared and the activity of its Ru(bpy)(2) complex as a photosensitizer for dye-sensitized solar cell application was investigated. The compounds reported illustrate the unusual reactivity of reduced pyrazinacenes and also their potential as photosensitizers.
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