期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 20-21, 页码 2090-2100出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201800226
关键词
Metal complexes; Self-healing; Responsive materials; Dynamic bonds; Supramolecular materials; Supramolecular chemistry
资金
- University of Strasbourg Institute for Advanced Study (USIAS)
Supramolecular functional materials featuring self-healing properties are a fascinating class of materials that are currently attracting great interest. In this respect, use of dynamic metal-ligand bonds has received much less attention than other reversible interactions - either covalent bonds or noncovalent interactions. Nonetheless, systems and materials with enhanced and special functionalities might arise from the synergic combination of labile coordination bonds and the physicochemical properties - optical, magnetic, electrical, catalytic, and so on - associated with the presence of judiciously chosen metal ions or organic ligands. Here, advances in the field of healing and multi-functional materials based on the reversible formation of metal-ligand bonds are highlighted through a selection of key examples, including bioinspired ones.
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