4.5 Article

A Nonlinear Optically Active Bismuth-Camphorate Coordination Polymer

期刊

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 20-21, 页码 2437-2443

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201800197

关键词

Coordination polymers; Synthesis design; Bismuth; Structure elucidation; Nonlinear optics

资金

  1. IMDEA Energy
  2. Raphuel project [ENE2016-79608-C2-1-R]
  3. Spanish Ramon y Cajal Programme [2014-16823]
  4. People Programme (Marie Curie Actions) of the European Union's Seventh Framework Programme (FP7) under REA grant [291803]
  5. Fund Scientific Flanders (FWO-Vlaanderen)
  6. KU Leuven [C16/16/003]

向作者/读者索取更多资源

The novel 2D bismuth-camphorate IEF-1, formulated as [Bi(L)(HL)] (where H2L = camphoric acid), has been successfully isolated as large single crystals and easily scaled up by hydrothermal synthesis. The crystalline structure of IEF-1 was unveiled by single-crystal X-ray diffraction, in the monoclinic space group P2(1), and fully characterized by using several standard solid-state techniques. IEF-1 material is thermally stable up to ca. 240 degrees C without any visible structural change. In addition, the study of the nonlinear optical (NLO) properties of IEF-1 by second harmonic generation (SHG) microscopy evidenced that IEF-1 is noncentrosymmetric and has a more intensive blue component that may be explained by the ligand to metal charge transfer behavior.

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