期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 20-21, 页码 2125-2138出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201800159
关键词
Hydrogen; Reaction mechanisms; Homogeneous catalysis; Dehydrogenation
资金
- Spanish Ministry of Economy and Competitiveness
- DGA/FSE-E07
- KFUPM-University of Zaragoza
- Centre of Research Excellence in Petroleum Refining KFUPM
The dehydrogenation of formic acid permits the production of hydrogen virtually free of carbon monoxide, which is a key requisite for its use in fuel cells. Moreover, HCOOH is a suitable hydrogen carrier, better in several crucial characteristics than other liquid organic hydrogen carriers, namely, low toxicity, high hydrogen content and recyclability (via CO2 hydrogenation). The most successfully employed catalysts are those based on Ir, Ru, Rh, and Fe metal centers. The catalytic cycles through which homogeneous metal complexes operate show a wide mechanistic diversity. The nature of catalytic cycle depends mainly on the nuclearity of the active species, the type of CO2 formation step (-hydride elimination, hydride abstraction, or outer-sphere mechanism), and whether the rate-limiting step relates to CO2 or H-2 formation. Different outer-sphere interactions have been proposed in the literature in order to explain the success of homogeneous catalyst, which seems to be common ground for most of the catalysts so far reported.
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