期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 5, 页码 547-560出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201701072
关键词
Oxidation; High-valent oxidants; Hydrogen atom transfer; Reaction mechanisms; Reactive intermediates
资金
- European Union [FP7-333948, ERC-2015-STG-678202]
- Science Foundation Ireland [SFI/15/RS-URF/3307]
High-valent metal-oxygen species (M-O-X species, as opposed to terminal metal-oxo, M=O, species) have been found to constitute a large family of capable oxidants. Herein, synthetic high-valent complexes with hydroxide, alkoxide and other anionic O-atom ligands, as well as O-Lewis acid adducts, are reviewed with a focus on their reactivity. Mn, Fe and Ru complexes are described, as well as recent additions to the field containing late transition metals (Co, Ni, Cu). These species are competent in a range of oxidations, and in particular they are capable of hydrogen atom transfer from strong C-H bonds. We explore how their reaction mechanisms and oxidising potency are modulated by the O-atom ligand.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据