期刊
FUEL
卷 153, 期 -, 页码 535-543出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2015.03.030
关键词
Bio-oil; Hydrodeoxygenation; Pyrolytic lignin; Noble metal catalyst; Catalyst reusability
资金
- Basic Science Research Program through the National Research Foundation (NRF) - Ministry of Education, Science and Technology [2013R1A2A2A01011112]
- National Research Foundation of Korea (NRF) - Ministry of Education [2014H1A2A1018117]
- National Research Council of Science and Technology of Korea
A hydrodeoxygenation reaction (HDO) of bio-oil was conducted with Ru/C and Pt/C. Yield of heavy oil as a target product was influenced by reaction temperature irrespective of catalysts. HDO gave rise to an improvement in the following oil properties: water content, heating value, viscosity, acidity and oxygen level. Due to the de-moisturization, 61.6-97.2% of water decreased. Ru/C and Pt/C led to deoxygenation with increasing temperature. Especially, the heavy oil obtained from 350 degrees C with Pt/C was deoxygenated up to 78.2% and had a higher heating value (27.8 MJ/kg) than the bio-oil (17.3 MJ/kg). After HDO unstable/unsaturated compounds (acetic acid, furfural, vanillin and levoglucosan) in bio-oil were converted to esters, ketones and saturated phenols. According to the reusability test of HDO catalysts chars were deposited on the surface of catalysts, which could be the reason for the deactivation of catalysts. The Pt/C was denoted as having high durability and thermal resistance. (C) 2015 Elsevier Ltd. All rights reserved.
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