Numerical and experimental studies on the ignition of pulverized coal in O2/H2O atmospheres

Oxy-fuel combustion is regarded as a promising technology for CO2 abatement in coal-fired power generation. Oxy-steam combustion technology is regarded as the next generation of oxy-fuel combustion technology because it has numerous advantages over O-2/CO2 recycled combustion. The ignition of coal particles was investigated using numerical and experimental analysis in O-2/N-2 and O-2/H2O atmospheres with different oxygen concentrations (21%, 30%, 35%, 40% and 50%). The experiments were performed in a drop tube furnace (DTF) using a high-speed camera. The experimental results show that the pulverized coal ignites homogeneously in both the O-2/H2O and O-2/N-2 atmospheres, and the ignition of pulverized coal occurs sooner in the O-2/H2O atmospheres than in the O-2/N-2 atmosphere with an identical O-2 mole fraction. The model proposed in the paper was validated by comparison of the predicted locations of the coal ignition with the experimental results. The effects of the physicochemical properties of H2O on the ignition of coal were analyzed in detail by numerical simulation. The results of numerical simulation showed that the steam shift reaction is the primary reason for the advanced ignition of coal in the O-2/H2O atmospheres compared with the corresponding O-2/N-2 atmospheres, and the steam gasification reaction is a minor reason for the phenomena because it produces CO and H-2, which are beneficial in the ignition. (C) 2014 Elsevier Ltd. All rights reserved.