期刊
FUEL
卷 150, 期 -, 页码 370-377出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2015.02.032
关键词
Ultrasonic; High acid value; Jatropha biodiesel; Magnetic catalyst; Na2SiO3@Fe3O4/C
资金
- Chinese Academy of Sciences [Bairenjihua, CAS 135 program] [XTBG-T02]
- Yunnan Provincial Government (Baiming Haiwai Gaocengci Rencai Jihua)
- Natural Science Foundation of China [31400518]
- Chinese Academy of Sciences [equipment RD grant] [YZ201260]
Magnetic heterogeneous catalyst (Na2SiO3@Fe3O4/C) was prepared for the production of biodiesel from oils with high acid value (AV) under ultrasonic (US) irradiation and magnetic stirring (MS). With the catalyst and assisted by US, soybean biodiesel yield reached >90% in only 20 min (or at 318 K) and 97.9% under the optimal conditions. It was easily magnetically separated for 5 cycles with 94.9% recovery rate and biodiesel yield >80% with both US and MS. The catalyst transesterified Jatropha oil with biodiesel yields of 94.7%, 93.2% and 83.5% at AV of 1.3, 4.8 and 7.3 (mg KOH/g) with US, and was cycled 5 times with yield >70% at AV of 4.8 assisted by US and MS. High biodiesel yield (90.7%) was still achieved from high AV oil (4.8) at low US energy density (0.1 W/mL) and MS. The catalyst combined with US and MS can find practical application for direct production of biodiesel from oils with high AV. (C) 2015 Elsevier Ltd. All rights reserved.
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