期刊
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
卷 25, 期 13, 页码 12419-12433出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s11356-018-1469-5
关键词
Persistence; Pre-emergence herbicides; Metabolites; Residues; Degradation; Mineralization
资金
- FAPESP Sao Paulo State Research Foundation
- CNPq-National Council for Scientific and Technological Development
The physicochemical properties of soil are fundamental to quantification of the fate of herbicides. Thus, the aim of this research was to evaluate the fate of diuron, hexazinone, and metribuzin in five soils (Clay-1, Clay-2, Loam-1, Loam-2, and Sand), presenting variation in clay content, cation exchange capacity (CEC), pH, and organic carbon (OC). Herbicides radiolabeled with C-14 were applied, and the C-14-CO2 released from mineralization was trapped in 0.2 mol L-1 sodium hydroxide solution. The degradation ratio, as well as herbicide-bound residues (non-extractable), transformation products, and residues extractable from soil, was also evaluated. Average C-14-CO2 evolution accumulated for diuron mineralization was higher (22.24%) than hexazinone (7.73%) and metribuzin (3.20%). The degradation time half-life (DT50) values for hexazinone correlated with soil OC content. Although no correlation between soil properties and DT50 values was found for metribuzin, the degradation rate and total degree of mineralization were low in sand soil for metribuzin. Regarding diuron, OC content and CEC value appear to be related to mineralization and degradation rate, respectively. Differences in soil properties can influence the persistence and fate of herbicides, affecting their impact on the environment, weed control, and possible effects on subsequent crops.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据