期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 11, 期 7, 页码 1870-1879出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ee00449h
关键词
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资金
- US Department of Energy [DE-SC0016965]
- US National Science Foundation [DMR-1506925, 1545907]
- Department of Energy's Office of Energy Efficiency and Renewable Energy (EERE) under the Fuel Cell Technologies Office (FCTO) [DE-EE 45 0008079]
- State Scholarship Fund of China Scholarship Council [201606285002]
- National Natural Science Foundation of China [51602248]
- AGNPCyT [PICT 2013-1032]
- CONICET
- Universidad Nacional de Cuyo
- Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource [NSF NNCI-1542205]
- MRSEC program at the Materials Research Center [NSF DMR-1121262]
- International Institute for Nanotechnology (IIN)
- Keck Foundation
- State of Illinois, through the IIN
- Direct For Mathematical & Physical Scien [1506925, 1506055] Funding Source: National Science Foundation
A key need in the development of solid oxide cells (SOCs) is for electrodes that promote fast oxygen reduction and oxygen evolution reactions at reduced operating temperature (700 degrees C), with sufficient durability to allow operation over desired 40000 h lifetimes. A wide range of electrode materials have been investigated, with some providing resistance low enough for cell operation below 700 degrees C, but it is generally found that the electrode performance degrades over time. Here we demonstrate an oxygen electrode material, Sr(Ti0.3Fe0.7-xCox)O3- (STFC), that provides a unique combination of excellent oxygen electrode performance and long-term stability. The addition of a relatively small amount of Co to Sr(Ti0.3Fe0.7)O3-, e.g., x = 0.07, reduces the electrode polarization resistance by >2 times. The STFC electrode yields stable performance in both fuel cell and electrolysis modes at 1 A cm(-2). The fundamental oxygen diffusion and surface exchange coefficients of STFC are determined, and shown to be substantially better than those of La0.6Sr0.4Co0.2Fe0.8O3-, the most widely used SOC oxygen electrode material. While other electrode materials have been shown to exhibit better oxygen transport coefficients than STFC, they do not match its stability.
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