期刊
RSC ADVANCES
卷 5, 期 75, 页码 61371-61379出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra11014a
关键词
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资金
- National Natural Science Foundation of China [51172265]
- Ministry of Science and Technology of China [2014AA032802]
- Education Commission of Shanghai Municipal [14ZZ099]
- Materials Genome Institute of Shanghai University [14DZ2261200]
- China Postdoctoral Science and Foundation [2014M561528]
- CSIRO Office of the Chief Executive (OCE) Postdoctoral Fellowship
Monocrystalline VO2(A) nanoplates have been synthesized via a one-pot hydrothermal process. In situ powder X-ray diffraction was used to monitor the hydrothermal synthesis and it was found that VO2(A) nucleates and grows directly from solution after the complete hydrolysis of a 2.0 M VO(acac)(2) precursor solution, rather than involving a previously reported intermediate phase VO2(B). A hydrating-exfoliating-splitting mechanism was established to explain the formation of the nanoplate architecture. The synthesized VO2(A) nanoplates showed outstanding peroxidase-like activity and hence are a promising candidate for artificial peroxidase.
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