期刊
ELECTROCHIMICA ACTA
卷 283, 期 -, 页码 1425-1431出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2018.07.092
关键词
Electrodeposition; Gold microflower; Electrocatalysts; Sensor
资金
- National Research Foundation of Korea (NRF) grant - Korea government (MISP) [2014R1A4A1008140]
- program for fostering nextgeneration researchers in the engineering of National Research Foundation of Korea (NRF) - Ministry of Education ICT [2017H1D8A2030449]
In the present work, we report a simple and facile templateless electrodeposition of hierarchical flowerlike gold microstructure which was synthesized by using a chronoamperometric (CA) i-t curve technique at a constant applied potential of E = 0.5 V with respect to sat Ag/AgCl (KCl) on indium tin oxide electrode (ITO) substrate. The surface morphology, elemental composition and the preferred orientation of gold microflowers (AuMFs) were characterized using scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) analyses. The SEM images of the as-prepared AuMFs resembled nanoflakes which are building block for the formation of a three dimensional hierarchical flower-like morphology. Surface elemental composition and valence state of AuMFs is further examined by X-ray photoelectron spectroscopy (XPS). The electrochemical oxidation behavior of AuMFs was investigated by using Cyclic Voltammetry (CV) and chronoamperometric CA techniques with the H2O2 analyst in 0.1 M phosphate buffer solution (pH 7.4). The AuMFs deposited ITO electrodes exhibited excellent electrocatalytic reactivity towards H2O2 oxidation due to the increase of in adsorption of H2O2 on gold-oxide surfaces and it was enhancing the amperometric sensing of H2O2 in neutral solutions. (C) 2018 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据